Depending on where a piece of clothing goes, you use a different verb 履く - below waist. Trousers, shoes 着る - on the upper body: Shirts 被る - on the head. Hats
掛ける- Stuff you put on top of something: glasses
For other pieces, or body parts in general use する：
時計をする。 To wear a watch
彼はいい太ももをしている He has a good butt
taking stuff off is always 脱ぐ